Belgium
From Visawiki - the Collaborative Guide to Visas
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Belgium is part of the Schengen area.
Brussels is the capital of Belgium and of the EU. Many countries have embassies in this city. A lot of countries don't have embassies in neighboring countries such as the Netherlands and Luxembourg, so if you're a resident of these countries Brussels can sometimes be a convenient option for acquiring visas.
Some countries with embassies: Mali, Afghanistan, Tajikistan...
